Adsorption of nicosulfuron herbicide in the agricultural soils of Bosnia and Herzegovina A., Mitric S., Sunjka D., Zabic M., Predic T., Sipka M., Rodic L. (2020): Adsorption of nicosulfuron herbicide in the agricultural soils of Bosnia and Herzegovina. Plant Soil Environ., 66: 162-166.
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In this study, the sorption characteristics of nicosulfuron herbicide in soils from different agricultural regions of Bosnia and Herzegovina, as well as factors influencing the sorption process, were evaluated. The analysis was performed using a batch equilibrium method. The obtained results showed that soils in Bosnia and Herzegovina are very versatile in terms of their characteristics. The Freundlich adsorption coefficient (Kf) coefficient ranged from 0.027 to 7.388, while the slope of the Freundlich isotherm (1/n) varied from 0.291 to 1.927. In soils with pH 4.31–7.60, 1/n was found to be less than 1 (0.337–0.547), and for the extremely alkaline soil with pH 8.2, 1/n was 1.927. Adsorption of nicosulfuron in the tested soils of Bosnia and Herzegovina was significantly correlated with the sand and silt content in the soil. Multiple linear regression correlating log Kf with the sand and silt content in the studied soils was also statistically significant (R2 = 0.951; P = 0.0108). The results of this study indicate that in sandy soils, which are slightly or moderately alkaline, the adsorption of nicosulfuron is very low and only a small amount of nicosulfuron will be adsorbed.

Ahmad K.S., Rashid N., Azhar S. (2016): Adsorption and desorption characteristics of chlorosulfuron in selected minerals and Pakistani soils. Eurasian Journal of Soil Science, 5: 1–12.
Azcarate M.P., Montoya J.C., Koskinen W.C. (2015): Sorption, desorption and leaching potential of sulfonylurea herbicides in Argentinean soils. Journal of Environmental Science and Health, Part B, 50: 229–237.
Battaglin W.A., Furlong E.T., Burkhardt M.R., Peter C.J. (2000): Occurrence of sulfonylurea, sulfonamide, imidazolinone, and other herbicides in rivers, reservoirs and ground water in the Midwestern United States, 1998. The Science of the Total Environment, 248: 123–133.
Beulke S., Brown C.D., Fryer C.J., van Beinum W. (2004): Influence of kinetic sorption and diffusion on pesticide movement through aggregated soils. Chemosphere, 57: 481–490.
Brown H.M. (1990): Mode of action, crop selectivity, and soil relations of the sulfonylurea herbicides. Pest Management Science, 29: 263–281.
Capri E., Camisa M.G., Glass R., Gonzalez-Pradas E., Trevisan M. (2001): Imidacloprid and pyrimethanil soil sorption. Agronomie, 21: 57–64.
Delgado-Moreno L., Peña A. (2007): Sorption/desorption behaviour of sulfonylurea herbicides as affected by the addition of fresh and composted olive cake to soil. Weed Research, 48: 461–469.
Delle Site A. (2001): Factors affecting sorption of organic compounds in natural sorbent/water systems and sorption coefficients for selected pollutants. A review. Journal of Physical and Chemical Reference Data, 30: 439.
Gonzalez J.M., Ukrainczyk L. (1996): Adsorption and desorption of nicosulfuron in soils. Journal of Environmental Quality, 25: 1186–1192.
Grahovac N., Stojanović Z., Kravić S., Orčić D., Suturović Z., Kondić-Špika A., Vasin J., Šunjka D., Jakšić S., Rajković M., Grahovac N. (2017): Determination of residues of sulfonylurea herbicides in soil by using microwave-assisted extraction and high performance liquid chromatographic method. Hemijska Industrija, 71: 289–298.
Kah M., Brown C.D. (2006): Adsorption of ionisable pesticides in soils. Reviews of Environmental Contamination and Toxicology, 188: 149–217.
Liu K., Cao Z., Pan X., Yu Y. (2012): Using in situ pore water concentrations to estimate the phytotoxicity of nicosulfuron in soils to corn (Zea mays L.). Environmental Toxicology and Chemistry, 31: 1705–1711.
McBean C. (2012): The Pesticide Manual: A World Compendium. 16th Edition. Alton, British Crop Production Council.
Oliveira Jr.R.S., Koskinen W.C., Ferreira F.A. (2001): Sorption and leaching potential of herbicides on Brazilian soils. Weed Research, 41: 97–110.
Predić T., Nikić-Nauth P., Tanasić B., Vidojević D. (2019): Organic carbon stocks in arable land of Republic of Srpska-Bosnia and Herzegovina. AGROFOR International Journal, 4: 70–77.
Rahman A., James T.K., Trolove M., Dowsett C. (2011): Factors affecting the persistence of some residual herbicides in maize silage fields. New Zealand Plant Protection, 64: 125–132.
Regitano J.B., Koskinen W.C. (2008): Characterization of nicosulfuron availability in aged soils. Journal of Agricultural and Food Chemistry, 56: 5801–5805.
Said-Pullicino D., Gigliotti G., Vella A. (2004): Environmental fate of triasulfuron in soils amended with municipal waste compost. Journal of Environmental Quality, 33: 1743–1751.
Sparks D. (2003): Environmental Soil Chemistry. San Diego, Academic Press. ISBN: 9780080494807
Trigo C., Spokas K.A., Cox L., Koskinen W.C. (2014): Influence of soil biochar aging on sorption of the herbicides MCPA, nicosulfuron, terbuthylazine, indaziflam, and fluoroethyldiaminotriazine. Journal of Agricultural and Food Chemistry, 62: 10855−10860.
Wauchope R.D., Yeh S., Linders J.B., Kloskowski R., Tanaka K., Rubin B., Katayama A., Kördel W., Gersti Z., Lane M., Unsworth J.B. (2002): Pesticide soil sorption parameters: theory, measurement, uses, limitations and reliability. Pest Management Science, 58: 419–445.
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