Optimisation of concurrent Calophyllum oil-resin extraction and separation

https://doi.org/10.17221/67/2020-RAECitation:

Kartika I.A., Cerny M., Vandenbossche V., Evon Ph., Trisunaryanti W., Mukti R.R., Hartati, Yuliana N.D., Sailah I. (2021): Optimisation of concurrent Calophyllum oil-resin extraction and separation. Res. Agr. Eng., 67: 84–91.

download PDF

This research optimised the application of a hexane-methanol mixture as a binary solvent for the concurrent oil-resin extraction and separation from Calophyllum seeds on a pilot scale, in a direct stage. The optimum oil and resin yields were determined by optimising the extraction conditions using response surface methodology and a second order polynomial model. The extraction conditions affected the oil and resin yields, with the extraction time as the biggest influencing factor. Optimum oil (65%) and resin (16%) yields were predicted to be obtained at 5.2 h and 433 rpm. The model validation with these extraction conditions showed that the predicted results and actual oil (62%) and resin (15%) yields were in passable agreement. The oil was composed of 75.4% triglycerides with a density of 0.874 g·cm–3, a viscosity of 26.4 mPa·s–1, an acid value of 46.4 mg KOH·g–1, an iodine value of 98.0 g iodine·100 g–1, trace water and sediment contents, and zero ash content. The resin had a viscosity of 4 694.8 mPa·s–1, a total phenolic content of a 4.51% gallic acid equivalent, an antioxidant activity of an 8.82 mg ascorbic acid equivalent·g–1, and an acid value of 126.2 mg KOH·g–1.

References:
Adewuyi A., Fasusi O.H., Odorinde R.A. (2014): Antibacterial activities of acetonides pre-pared from the seed oils of Calophyllum inophyllum and Pterocarpus osun. Journal of Acute Medicine, 4: 75–80. https://doi.org/10.1016/j.jacme.2014.02.001
 
Arumugam A., Ponnusami V. (2019): Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview. Renewable Energy, 131: 459–471. https://doi.org/10.1016/j.renene.2018.07.059
 
Boucher C. (2000): Calophyllum oil extracted at ambient temperature has UV protecting, antiradical, antioxidant, anti aging and therapeutic properties. France Patent FR9907772A. Dec 22, 2000.
 
Dai J., Mumper R.J. (2010): Plant phenolics: Extraction, analysis and their antioxidant and anticancer properties. Molecules, 15: 7313–7352. https://doi.org/10.3390/molecules15107313
 
Dweck A.C., Meadows T. (2002): Tamanu (Calophyllum inophyllum)-The African, Asian, Polynesian and Pacific Panacea. International Journal of Cosmetic Science, 24: 1–8. https://doi.org/10.1046/j.1467-2494.2002.00160.x
 
Ginigini J., Lecellier G.J., Nicolas M., Nour M., Hnawia E., Lebouvier N., Herbette G., Lockhart P., Raharivelomanana P. (2019): Chemodiversity of Calophyllum inophyllum L. oil bioactive components related to their specific geographical distribution in the South Pa-cific region. PeerJ, 7: e6896.
 
Indartono Y.S., Heriawan H., Kartika I.A. (2019): Innovative and flexible single screw press for the oil extraction of Calophyllum seeds. Research in Agricultural Engineering, 65: 91–97. https://doi.org/10.17221/85/2018-RAE
 
Jahirul M.I., Brown R.J., Senadeera W., Ashwath N., Rasul M.G., Rahman M.M., Hossain F.M., Moghaddam L., Islam M.A., O'Hara I.M. (2015): Physio-chemical assessment of beauty leaf (Calophyllum inophyllum) as second-generation biodiesel feedstock. Energy Reports, 1: 204–215. https://doi.org/10.1016/j.egyr.2015.10.003
 
Jain M., Chandrakant U., Orsat V., Raghavan V. (2018): A review on assessment of biodiesel production methodologies from Calophyllum inophyllum seed oil. Industrial Crops and Products, 114: 28–44. https://doi.org/10.1016/j.indcrop.2018.01.051
 
Kartika A.I., Yani M., Ariono D., Evon P., Rigal L. (2013): Biodiesel production from jatropha seeds: Solvent extraction and in situ transesterification in a single step. Fuel, 106: 111–117. https://doi.org/10.1016/j.fuel.2013.01.021
 
Kartika I.A., Bernia O.T.O., Sailah I., Prakoso T., Purwanto Y.A. (2019): A binary solvent for the simultaneous Calophyllum oil-resin extraction and purification. Research in Agricul-tural Engineering, 65: 63–69. https://doi.org/10.17221/30/2018-RAE
 
Kartika A.I., Evon P., Cerny M., Suparno O., Hermawan D., Ariono D., Rigal L. (2016): Simultaneous solvent extraction and transesterification of jatropha oil for biodiesel produc-tion, and potential application of the obtained cakes for binderless particleboard. Fuel, 181: 870–877. https://doi.org/10.1016/j.fuel.2016.05.038
 
Kartika A.I., Cerny M., Vandenbossche V., Rigal L., Sablayrolles C., Vialle C, Suparno O., Ariono D., Evon Ph. (2018): Direct Calophyllum oil extraction and resin separation with a binary solvent of n-hexane and methanol mixture. Fuel, 221: 159–164.  https://doi.org/10.1016/j.fuel.2018.02.080
 
Kolb J.P., Menasria F., Billard C., Meyer M., Azebaze A.G., Nkengfack A.E. (2011): Use of xanthone derivatives as a medicament for cancer. US Patent US20110263694A1. Oct 27, 2011.
 
Lee C.G., Seng C.E., Liew K.Y. (2000): Solvent efficiency for oil extraction from spent bleaching clay. Journal of the American Oil Chemists' Society, 77: 1219–1222. https://doi.org/10.1007/s11746-000-0190-6
 
Léguillier T., Lecsö-Bornet M., Lémus C., Rousseau-Ralliard D., Lebouvier N., Hnawia E., Nour M., Aalbersberg W., Ghazi K., Raharivelomanana P., Rat P. (2015): The wound heal-ing and antibacterial activity of five ethno medical Calophyllum inophyllum oils: An alterna-tive therapeutic strategy to treat infected wounds. PLoS ONE, 10: e0138602.
 
Liu W., Liu Y., Chen Z., Chiou W., Tsai Y., Chen C. (2015): Calophyllolide content in Calophyllum inophyllum at different stages of maturity and its osteogenic activity. Mole-cules, 20: 12314–12327. https://doi.org/10.3390/molecules200712314
 
Montgomery D.C. (2001): Design and Analysis of Experiments. 5th Ed. New York, John Wiley & Sons, Inc.
 
Nariya P.B., Bhalodia N.R., Shukla V.J., Acharya R., Nariya M.B. (2013): In vitro evaluation of antioxidant activity of Cordia dichotoma (Forst f.) bark. AYU An International Quarterly Journal of Research in Ayurveda, 34: 124–128. https://doi.org/10.4103/0974-8520.115451
 
download PDF

© 2021 Czech Academy of Agricultural Sciences | Prohlášení o přístupnosti